e/Schmidt reaction

Information
has gloss	eng: The Schmidt reaction is an organic reaction involving alkyl migration over the carbon to nitrogen chemical bond in an azide with expulsion of nitrogen. A key reagent introducing this azide group is hydrazoic acid and the reaction product depends on the type of reactant: carboxylic acids form amines through an isocyanate intermediate (1) and ketones form amides (2):
lexicalization	eng: Schmidt reaction
instance of	e/Rearrangement reaction

Meaning
German
has gloss	deu: Mittels der Schmidt-Reaktion können Carbonsäuren zu primären Aminen, Ketone zu Carbonsäureamiden abgebaut werden.
lexicalization	deu: Schmidt-Reaktion
Japanese
has gloss	jpn: シュミット反応(—はんのう、Schmidt reaction)は化合物を酸性条件下においてアジ化水素で処理した際に起こる化学反応のことである。いずれも転位反応であるため、シュミット転位(—てんい、Schmidt rearrangement)とも呼ばれる。
lexicalization	jpn: シュミット反応
Portuguese
has gloss	por: A reação de Schmidt é uma reação orgânica envolvendo migração da ligação química de alquila do carbono para o nitrogênio em uma azida com a expulsão do nitrogênio. Um reagente chave indroduczindo este grupo azida é o ácido hidrazóico e o produto da reação depende do tipo de reagente: ácidos carboxílicos formam aminas através de um intermediário isocianato:
lexicalization	por: reação de Schmidt
Chinese
has gloss	zho: 施密特反应（Schmidt反应）是一个有机重排反应，原料在叠氮酸作用下，放出氮气，发生烷基迁移生成新的C-N键。以羧酸作原料时，经由异氰酸酯中间体，产物为少一个碳的胺：
lexicalization	zho: 施密特反应

Media
media:img	BoyerReaction.png
media:img	Schmidt-Rxn Ketonen.svg
media:img	Schmidt-Rxn mit Carbonsäuren.svg
media:img	Schmidt.png
media:img	SchmidtReaction carboxylicAcid.png
media:img	SchmidtreactionAmines.png
media:img	SchmidtreactionApplication.png
media:img	SchmidtreactionmechanismAmide.png
media:img	Schmidtreactionmechanismamine.png